Application of the surface complex formation model to exchange equilibria on ion exchange resins. After elutriation the iminodiacetic acid ida chelating resin was synthesized, and the infrared spectrum of the product indicated that the synthetic reaction is effective. The iminodiacetic acid chelating resin amberlite irc748 was purchased from rohm and haas. In the preparation of chelating resins with glycidyl methacrylate for the selective removal and recovery of metal ions from industrial waste water. An iminodiacetic acidtype chitosan chelating resin selectively adsorbed germaniumiv from aqueous solutions over the range of strongly acidic to weakly basic media. The effects of anions and the number of iminodiacetic acid groups per unit weight of resins were also discussed. Ambersep irc748 upsresin also exhibits high selectivity for heavy metal cations over alkali metal ions found in various process and waste streams. Distribution coefficients of metal ions in the presence of sulfosalicylic acid and citric acid were calculated in order to determine the proper ph for the most efficient separations. This overview discusses chelating resin applications to recover copper, nickel, and cobalt from mining process and mining tailings and the effect of contaminants in leach solution. Adsorption mechanism of trivalent metal ions on chelating resins. More particularly, the present invention is concerned with macroporous, aminoalkylphosphonic or iminodiacetic acid chelating resins having improved stability and capacity in the removal of cations e. Chelex 100 and chelex 20 chelating ion exchange resin. The separation and recovery of radiostrontium from simulated alkaline reprocessing waste solution has been studied using amberlite irc.
The typical properties of amberlite irc748 are shown below. Puromet mts9300iminodiacetic acid chelating resinlenntech. The structure offers selective binding of recombinant his tagged proteins when this resin is charged with transition metals. Separation of metal ions on chelating resin abstract attempts were made to separate components of metal ion mixtures on columns of iminodiacetate type chelating resin. Figure 3 regeneration of a chelating resin may require a complexing eluant. Iminodiacetic acid ida is an polyamino carboxylic acid. With the cas registry number 142734, it is also named as 2,2 iminodiacetic acid. The iminodiacetate anion can act as a tridentate ligand to form a metal complex with two, fused, five membered chelate rings. Before use the resin was washed with distilled water for 24h, dried on a stove at 355c, and preequilibrated with sulphuric acid solution h 2 so 4 0. Synthesis of chelating resins by attachment of iminodiacetic acid to a. Adsorption properties of a chelating resin containing hydroxy.
Application of a simple thermodynamic model to various ion exchange data. Selective separation of indium by iminodiacetic acid. The tertiary amine and carboxylic acid side chains of ida serve as the chelating ligands for di or trivalent metal ions. At very low ph, the resin acts as an anion exchanger. Adsorption properties of a chelating resin containing. A crosslinked chelating ion exchange resin containing two iminodiacetic acid ida. The iminodiacetic acid is an organic compound with the formula c 4 h 7 no 4. Chelex chelating ion exchange resin has unusually high preference.
Purolite s930plus is a polystyrenic macroporous iminodiacetic acid chelating resin ideal for brine decalcification. Extraction of uranium from nonsaline and hypersaline. Chelating resins with iminodiacetate functional group can be used for selective copper recovery, and both iminodiacetate and bispicolylamine resins are highly. Iminodiacetic acid chelating resin, high capacity product data sheet. If you are using immobilizedmetal affinity chromatography imac to purify proteins, there is a good chance your metal ion is coupled to the resin matrix via either nitrilotriacetic acid nta or iminodiacetic acid ida. A macroporous iminodiacetic acid resin, xe318, is presently being. The breakthrough behavior of strontium has been determined by conducting an extended column run. Feb 03, 1976 for producing the phenolic chelate resin having selective absorbability to heavy metal ions from a phenol, an aldehyde, and iminodiacetic acid, a 5 to 90, preferably 20 to 70 wt% aqueous suspension of a mixture of the three components is heated to 20 to 90c, preferably 40 to 60c to uniformly suspend the iminodiacetic acid in the. English french german italian polish portuguese romanian russian spanish here to help. This paper investigates the adsorption characteristics of indium and iron on an iminodiacetic acid chelating resin, amberliteirc748 rohm and haas co. Yield, properties, and practical usefulness of the products were compared. A macroporous, chelating ion exchange resin, which comprises a copolymer comprising 86 to 94 percent by weight of units of monovinyl aromatic monomer, 4 to 8 percent by weight of units of divinyl aromatic monomer and 2 to 6 percent by weight of units of oxygencontaining crosslinker, and wherein the copolymer is functionalized with aminoalkylphosphonic or iminodiacetic acid groups.
The major functional groups, carboxylate acid group, of the resin were verified by ftir spectroscopy. Purolite s108polystyrenic macroporous, iminodiacetic acid. Iminodiacetic acid article about iminodiacetic acid by the. Showing metabocard for iminodiacetic acid hmdb0011753. Iminodiacetic acid ida and nitrilotriacetic acid nta are widely used to fix transition metal ions to a matrix, which then serves as an affinity resin.
As a service to our customers we are providing this early version of. Adsorption mechanism of trivalent metal ions on chelating. The characteristic functional groups and chemical composition of psgi were analyzed by fourier transform infrared spectroscopy and elemental analysis of c, h, and n. Article pdf available in brazilian journal of chemical engineering 242 april 2007 with. Chelex chelating resin is classed with the weakly acidic cation exchange resins by virtue of its carboxylic acid groups, but it differs from ordinary exchangers because of its high selectivity for metal ions and its much higher bond strength. Nitrilotriacetic acid is mainly used as a chelating and eluting agent and is found in laundry detergents. The present invention relates to aluminumdoped chelate resins containing iminodiacetic acid groups, to a production process for aluminumdoped chelate resins containing iminodiacetic acid groups, and to a device comprising at least one layer of at least one aluminumdoped chelate resin containing iminodiacetic acid groups, and to the uses of this device and of the chelate resins for removal. The proton on the nitrogen atom can be replaced by a carbon atom of a polymer to create an ionexchange resin, such as chelex 100. Synthesis of chelating resins with iminodiacetic acid and its. There are other chelating ligand used for imac resins, but nta and ida are the popular ones. Polystyrenecodivinylbenzenepamamida chelating resin.
Polystyrenic macroporous, iminodiacetic acid chelating resin, high capacity. Ambersep irc748 ups chelating resin is a macroreticular, iminodiacetic acid chelating cation exchange resin with high selectivity for calcium, magnesium and strontium in chloralkali brines. Chelex chelating resin is efficiently regenerated in dilute acid and operates in basic, neutral, and. An iminodiacetic acid type chitosan chelating resin selectively adsorbed germaniumiv from aqueous solutions over the range of strongly acidic to weakly basic media. Dowex chelating resin a1, also known as chelex 100, is based on iminodiacetic acid in a styrenedivinylbenzene matrix. Selective separation of indium by iminodiacetic acid chelating resin.
Multielemental elution behavior of metal ions adsorbed on. Dowex a1 is produced from chloromethylated styrene. Adsorption curves, measured under the conditions of metal ions in excess against chelating groups, directly indicated the metaltoligand ratio of the complexes formed in the resin phase. In the present work, we investigated the multielemental elution behavior of metal ions absorbed on iminodiacetic acid ida chelating resin by using hydrogen peroxide h 2 o 2 as an eluent. The cobalt chelating resin uses ida iminodiacetic acid as its functional ligand. Synthesis of chelating resins with iminodiacetic acid and. Our alwaysready technical support and service teams go the extra step to be your most trusted resource. Copperiiiminodiacetic acid chelating resin as a stationary. Indium can be recovered by treating residues, flue dusts, slags, and metallic intermediates in zinc smelting.
The iupac name of this chemical is 2carboxymethylaminoacetic acid. Sorption mechanism of trace amounts of divalent metal ions on a chelating resin containing iminodiacetate groups. The synthesis, characterization, and application of chelating ion. Recovery of nickel from orimulsion fly ash by iminodiacetic. The chelating resin pida was obtained by crosslinking of iminodiacetic acid modified glycidyl methacrylate during radical polymerization.
The resulting resin with iminoacetic acid functions showed rapid chelating abilities for transition metal ions such as zn ii, cd ii, cu ii, ni ii, co ii, and fe iii ions. The present invention is concerned with improved chelating resins. C4h7no4 a crystalline substance used as an intermediate in the manufacture of chelating agents, surfaceactive agents, and complex salts. Ida, dvb, and styrene for the removal of cuii, coii, and cdii from an aqueous solution. Iminodiacetic acid ida is widely used as a chemical intermediate and a chelating reagent for the production of glyphosate herbicides, electroplating solutions, chelating resin, surfactants. Indium ions adsorbed onto the polymeric resin were eluted with a 0. Iminodiacetic acid, hn ch 2 co 2 h 2, often abbreviated to ida, is a dicarboxylic acid amine the nitrogen atom forms a secondary amino group, not an imino group as the name suggests. Purolite s108polystyrenic macroporous, iminodiacetic acid chelating resin, high capacity, potable water grade lenntech created date. In contrast, other metal ions were rarely recovered.
The acid leaching and the oxidationprecipitation of vanadium have been conducted under conditions used in a previous work vitolo et al. Amberlite irc748 is an iminodiacetic acid chelating cation exchange resin with high. Chelex chelating resin is efficiently regenerated in dilute acid and operates in basic, neutral, and weakly acidic solutions of ph 4 or higher. Thermal analysis shows that it has good thermal stability at about 200c. Purolite s108polystyrenic macroporous, iminodiacetic acid chelating resin, high capacity, potable water grade lenntech keywords. As a catalyst along with iron fecl 3 complexes for methyl methacrylate mma polymerization. The hydrophilic acrylate monomer with the iminodiacetic acid chelating group was prepared from glycidyl methacrylate and iminodiacetic acid at 60c. Poly styrene sulfonamides with edtalike chelating groups.
A chelating ionexchange resin, amberlite irc 748 which carries an iminodiacetate acid functional group has been investigated for its adsorption properties towards ni, co, mn and mg from aqueous solution. Figure 1 shows the zwitterionic forms of the chelex resin as a function of ph. In the preparation of iminodiacetic acid idatype adsorbent for protein purification. Dowex a1 is available commercially and is widely used to determine general properties of chelating resins such as rate determining step and ph dependence, etc. Us20160347632a1 novel aluminumdoped, iminodiacetic acid. Different generations of pamam were used to obtain different chelating resins, psida, ps1. As a service to our customers we are providing this early version of the manuscript.
At the neutral phs the chelating resin was able to reduce the metal ion concentrations lower than 1 ppm in about 15 min of the contacting time. This consists of a preliminary acid leaching, oxidation and precipitation of vanadium as vanadium pentoxide, v 2 o 5, removal of iron and finally recovery of nickel by chelating resin. Comparative study of the application of chelating resins for. Pdf selective separation of germaniumiv by iminodiacetic. Nitrilotriacetic acid is a white, crystalline solid compound. Ambersep m4195 chelating resin product data sheet dupont. Applications of chelating resin for heavy metal removal from.
The two ligands differ in the number of valencies with which they coordinate the metal ion ida is trivalent, whereas nta is tetravalent. Experiments were conducted through batch adsorption by varying the resin volume at three different ph values. As a result, vv, movi, wvi, nbv and tav were efficiently eluted by h 2 o 2. The chelating resins have high potential applications for the selective removal and recovery of metal ions from industrial waste solutions. A chelating resin, psgi, was synthesized by the radical polymerization of gma. Computer techniques for identifying low resolution mass spectra.
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