In the preparation of iminodiacetic acid idatype adsorbent for protein purification. Synthesis of chelating resins with iminodiacetic acid and its. Adsorption mechanism of trivalent metal ions on chelating resins. A crosslinked chelating ion exchange resin containing two iminodiacetic acid ida. The present invention relates to aluminumdoped chelate resins containing iminodiacetic acid groups, to a production process for aluminumdoped chelate resins containing iminodiacetic acid groups, and to a device comprising at least one layer of at least one aluminumdoped chelate resin containing iminodiacetic acid groups, and to the uses of this device and of the chelate resins for removal. This paper investigates the adsorption characteristics of indium and iron on an iminodiacetic acid chelating resin, amberliteirc748 rohm and haas co. Chelex 100 and chelex 20 chelating ion exchange resin. Us20160347632a1 novel aluminumdoped, iminodiacetic acid.
Ambersep irc748 upsresin also exhibits high selectivity for heavy metal cations over alkali metal ions found in various process and waste streams. With the cas registry number 142734, it is also named as 2,2 iminodiacetic acid. The chelating resins have high potential applications for the selective removal and recovery of metal ions from industrial waste solutions. The major functional groups, carboxylate acid group, of the resin were verified by ftir spectroscopy. Indium can be recovered by treating residues, flue dusts, slags, and metallic intermediates in zinc smelting.
Polystyrenecodivinylbenzenepamamida chelating resin. Chelex chelating resin is efficiently regenerated in dilute acid and operates in basic, neutral, and weakly acidic solutions of ph 4 or higher. At very low ph, the resin acts as an anion exchanger. A macroporous iminodiacetic acid resin, xe318, is presently being. Adsorption curves, measured under the conditions of metal ions in excess against chelating groups, directly indicated the metaltoligand ratio of the complexes formed in the resin phase.
English french german italian polish portuguese romanian russian spanish here to help. The iminodiacetic acid is an organic compound with the formula c 4 h 7 no 4. Separation of metal ions on chelating resin abstract attempts were made to separate components of metal ion mixtures on columns of iminodiacetate type chelating resin. As a service to our customers we are providing this early version of. The separation and recovery of radiostrontium from simulated alkaline reprocessing waste solution has been studied using amberlite irc. Showing metabocard for iminodiacetic acid hmdb0011753. In the present work, we investigated the multielemental elution behavior of metal ions absorbed on iminodiacetic acid ida chelating resin by using hydrogen peroxide h 2 o 2 as an eluent.
Experiments were conducted through batch adsorption by varying the resin volume at three different ph values. However, the more complex, challenging electrolytes require the higher selectivity of. The proton on the nitrogen atom can be replaced by a carbon atom of a polymer to create an ionexchange resin, such as chelex 100. Iminodiacetic acid ida is an polyamino carboxylic acid. Exposure to nitrilotriacetic acid irritates the skin, eyes and respiratory tract and causes kidney and bladder damage. Pdf selective separation of indium by iminodiacetic acid chelating. Multielemental elution behavior of metal ions adsorbed on. The acid leaching and the oxidationprecipitation of vanadium have been conducted under conditions used in a previous work vitolo et al. Determination of molybdate in environmental water by ion.
This consists of a preliminary acid leaching, oxidation and precipitation of vanadium as vanadium pentoxide, v 2 o 5, removal of iron and finally recovery of nickel by chelating resin. In contrast, other metal ions were rarely recovered. At the neutral phs the chelating resin was able to reduce the metal ion concentrations lower than 1 ppm in about 15 min of the contacting time. The effects of anions and the number of iminodiacetic acid groups per unit weight of resins were also discussed. The present invention is concerned with improved chelating resins. The nickel chelating resin uses ida iminodiacetic acid as its functional ligand.
Comparative study of the application of chelating resins for. C4h7no4 a crystalline substance used as an intermediate in the manufacture of chelating agents, surfaceactive agents, and complex salts. Dowex a1 is available commercially and is widely used to determine general properties of chelating resins such as rate determining step and ph dependence, etc. The two ligands differ in the number of valencies with which they coordinate the metal ion ida is trivalent, whereas nta is tetravalent. Ambersep irc748 ups chelating resin is a macroreticular, iminodiacetic acid chelating cation exchange resin with high selectivity for calcium, magnesium and strontium in chloralkali brines. Iminodiacetic acid chelating resin, high capacity product data sheet. Polystyrenic macroporous, iminodiacetic acid chelating resin, high capacity. Iminodiacetic acid ida is widely used as a chemical intermediate and a chelating reagent for the production of glyphosate herbicides, electroplating solutions, chelating resin, surfactants. The hydrophilic acrylate monomer with the iminodiacetic acid chelating group was prepared. Applications of chelating resin for heavy metal removal from. Synthesis of chelating resins with iminodiacetic acid and. As a service to our customers we are providing this early version of the manuscript. The tertiary amine and carboxylic acid side chains of ida ser ve a s the chelating ligands for di or trivalent metal ions. Dowex a1 is produced from chloromethylated styrene.
Before use the resin was washed with distilled water for 24h, dried on a stove at 355c, and preequilibrated with sulphuric acid solution h 2 so 4 0. The breakthrough behavior of strontium has been determined by conducting an extended column run. Chelex chelating ion exchange resin has unusually high preference. Purolite s930plus is a polystyrenic macroporous iminodiacetic acid chelating resin ideal for brine decalcification. Sorption mechanism of trace amounts of divalent metal ions on a chelating resin containing iminodiacetate groups. In the preparation of chelating resins with glycidyl methacrylate for the selective removal and recovery of metal ions from industrial waste water. The characteristic functional groups and chemical composition of psgi were analyzed by fourier transform infrared spectroscopy and elemental analysis of c, h, and n. After elutriation the iminodiacetic acid ida chelating resin was synthesized, and the infrared spectrum of the product indicated that the synthetic reaction is effective. More particularly, the present invention is concerned with macroporous, aminoalkylphosphonic or iminodiacetic acid chelating resins having improved stability and capacity in the removal of cations e. The hydrophilic acrylate monomer with the iminodiacetic acid chelating group was prepared from glycidyl methacrylate and iminodiacetic acid at 60c. Indium ions adsorbed onto the polymeric resin were eluted with a 0. Iminodiacetic acid, hn ch 2 co 2 h 2, often abbreviated to ida, is a dicarboxylic acid amine the nitrogen atom forms a secondary amino group, not an imino group as the name suggests. Adsorption properties of a chelating resin containing hydroxy. Poly styrene sulfonamides with edtalike chelating groups.
This overview discusses chelating resin applications to recover copper, nickel, and cobalt from mining process and mining tailings and the effect of contaminants in leach solution. As a result, vv, movi, wvi, nbv and tav were efficiently eluted by h 2 o 2. Ida, dvb, and styrene for the removal of cuii, coii, and cdii from an aqueous solution. The typical properties of amberlite irc748 are shown below. Amberlite irc748 is an iminodiacetic acid chelating cation exchange resin with high. The iminodiacetate anion can act as a tridentate ligand to form a metal complex with two, fused, five membered chelate rings. Purolite s108polystyrenic macroporous, iminodiacetic acid. A chelating ionexchange resin, amberlite irc 748 which carries an iminodiacetate acid functional group has been investigated for its adsorption properties towards ni, co, mn and mg from aqueous solution. Purolite s108polystyrenic macroporous, iminodiacetic acid chelating resin, high capacity, potable water grade lenntech keywords. Our alwaysready technical support and service teams go the extra step to be your most trusted resource. If you are using immobilizedmetal affinity chromatography imac to purify proteins, there is a good chance your metal ion is coupled to the resin matrix via either nitrilotriacetic acid nta or iminodiacetic acid ida. As a catalyst along with iron fecl 3 complexes for methyl methacrylate mma polymerization. Synthesis of chelating resins by attachment of iminodiacetic acid to a.
There are other chelating ligand used for imac resins, but nta and ida are the popular ones. Yield, properties, and practical usefulness of the products were compared. An iminodiacetic acid type chitosan chelating resin selectively adsorbed germaniumiv from aqueous solutions over the range of strongly acidic to weakly basic media. Application of the surface complex formation model to exchange equilibria on ion exchange resins. Purolite s108polystyrenic macroporous, iminodiacetic acid chelating resin, high capacity, potable water grade lenntech created date. Distribution coefficients of metal ions in the presence of sulfosalicylic acid and citric acid were calculated in order to determine the proper ph for the most efficient separations.
Article pdf available in brazilian journal of chemical engineering 242 april 2007 with. The synthesis, characterization, and application of chelating ion. The cobalt chelating resin uses ida iminodiacetic acid as its functional ligand. Application of a simple thermodynamic model to various ion exchange data. Copperiiiminodiacetic acid chelating resin as a stationary. The resulting resin with iminoacetic acid functions showed rapid chelating abilities for transition metal ions such as zn ii, cd ii, cu ii, ni ii, co ii, and fe iii ions. Extraction of uranium from nonsaline and hypersaline. Pdf selective separation of germaniumiv by iminodiacetic. Thermal analysis shows that it has good thermal stability at about 200c. Chelex chelating resin is classed with the weakly acidic cation exchange resins by virtue of its carboxylic acid groups, but it differs from ordinary exchangers because of its high selectivity for metal ions and its much higher bond strength. Adsorption properties of a chelating resin containing.
Nitrilotriacetic acid is a white, crystalline solid compound. Figure 1 shows the zwitterionic forms of the chelex resin as a function of ph. Iminodiacetic acid article about iminodiacetic acid by the. A chelating resin, psgi, was synthesized by the radical polymerization of gma. Ambersep m4195 chelating resin product data sheet dupont. Dowex chelating resin a1, also known as chelex 100, is based on iminodiacetic acid in a styrenedivinylbenzene matrix. Selective separation of indium by iminodiacetic acid. Puromet mts9300iminodiacetic acid chelating resinlenntech. A macroporous, chelating ion exchange resin, which comprises a copolymer comprising 86 to 94 percent by weight of units of monovinyl aromatic monomer, 4 to 8 percent by weight of units of divinyl aromatic monomer and 2 to 6 percent by weight of units of oxygencontaining crosslinker, and wherein the copolymer is functionalized with aminoalkylphosphonic or iminodiacetic acid groups. Figure 3 regeneration of a chelating resin may require a complexing eluant.
Feb 03, 1976 for producing the phenolic chelate resin having selective absorbability to heavy metal ions from a phenol, an aldehyde, and iminodiacetic acid, a 5 to 90, preferably 20 to 70 wt% aqueous suspension of a mixture of the three components is heated to 20 to 90c, preferably 40 to 60c to uniformly suspend the iminodiacetic acid in the. Chelex chelating resin is efficiently regenerated in dilute acid and operates in basic, neutral, and. Chelating resins with iminodiacetate functional group can be used for selective copper recovery, and both iminodiacetate and bispicolylamine resins are highly. Nitrilotriacetic acid is mainly used as a chelating and eluting agent and is found in laundry detergents. An iminodiacetic acidtype chitosan chelating resin selectively adsorbed germaniumiv from aqueous solutions over the range of strongly acidic to weakly basic media. Adsorption mechanism of trivalent metal ions on chelating. The structure offers selective binding of recombinant his tagged proteins when this resin is charged with transition metals. The iminodiacetic acid chelating resin amberlite irc748 was purchased from rohm and haas.
Selective separation of indium by iminodiacetic acid chelating resin. Iminodiacetic acid ida and nitrilotriacetic acid nta are widely used to fix transition metal ions to a matrix, which then serves as an affinity resin. The iupac name of this chemical is 2carboxymethylaminoacetic acid. Comparative study of the application of chelating resins. Different generations of pamam were used to obtain different chelating resins, psida, ps1.
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